A reaction scheme showing an aryl aldehyde and a primary amine coming together on the left, with an arrow labeled with ...
One of the central challenges for synthetic chemists is to impose control over free radicals. Highly reactive molecules with an unpaired electron, free radicals may be familiar to you; these are the ...
Radical chemistry in aqueous solutions encompasses the study of highly reactive species generated in water, which play critical roles in biological, environmental and industrial processes. In such ...
The study of gas phase radical chemistry and spectroscopy has emerged as a cornerstone in understanding the fundamental reactivity of transient species. Radicals—molecules bearing unpaired ...
It is a truth universally acknowledged in chemical synthesis that a molecule in posession of multiple stereocenters must be difficult to make. But the combined abilities of biochemistry and radical ...
How the radical scavenger TEMPO traps a hydroxyl radical OH·. The proton of the hydroxyl radical reacts with TEMPO first. Colour coding: grey for C (carbon), white for H (hydrogen), red for O (oxygen) ...
Using muon spin rotation spectroscopy, researchers from Japan and Canada successfully captured the rapid conversion of an imidoyl radical into a quinoxalinyl radical occurring within nanoseconds. The ...
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UV-exposed water creates hydroxyl radicals via unexpected reaction path
Water treatment plants across the globe rely on ultraviolet light to generate hydroxyl radicals, the aggressive molecular ...
High levels of hydroxyl radicals (OH) can be generated indoors, simply due to the presence of people and ozone. People typically spend 90 percent of their lives inside, at home, at work, or in ...
You wouldn’t think that a paper published in 1900 in the Journal of the American Chemical Society with a rather unimposing title, An Instance of Trivalent Carbon: Triphenylmethyl, would have a huge ...
One of the central challenges for synthetic chemists is to impose control over free radicals. Highly reactive molecules with an unpaired electron, free radicals may be familiar to you; these are the ...
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